Factors Influencing Study Abroad Participation Among Binghamton University Students

Binghamton University (BUS)\u27s Office of International Programs (OIP) offers almost 30 study abroad programs. Increasing BU students\u27 study abroad participation is one of the ways by which the University aims to increase students\u27 preparation for a global society (Binghamton University, Office of the Provost 2010b,p.12).The OIP has continually strives to increase students\u27 study abroad participation, with an objective of increasing the percentage of the University\u27s graduating class that study abroad to 25%; however, it has not yet met its objective. This study examines the factors (both student-related and institutional-related) that influence BU undergraduate students\u27 participation in study abroad programs

Reconstructing the accumulation history of a saltmarsh sediment core: which age-depth model is best?

Saltmarsh-based reconstructions of relative sea-level (RSL) change play a central role in current efforts seeking to quantify the relationship between climate and sea-level rise. The development of an accurate chronology is pivotal, since errors in age-depth relationships will propagate to the final record as alterations in both the timing and magnitude of reconstructed change. A range of age-depth modelling packages are available but differences in their theoretical basis and practical operation mean contrasting accumulation histories can be produced from the same dataset. We compare the performance of five age-depth modelling programs (Bacon, Bchron, Bpeat, Clam and OxCal) when applied to the kinds of data used in high resolution, saltmarsh-based RSL reconstructions. We investigate their relative performance by comparing modelled accumulation curves against known age-depth relationships generated from simulated stratigraphic sequences. Bpeat is particularly sensitive to non-linearities which, whilst maximising the detection of small rate changes, has the potential to generate spurious variations, particularly in the last 400 years. Bacon generally replicates the pattern and magnitude of change but with notable offsets in timing. Bchron and OxCal successfully constrain the known accumulation history within their error envelopes although the best-fit solutions tend to underestimate the magnitude of change. The best-fit solutions of Clam generally replicate the timing and magnitude of changes well, but are sensitive to the underlying shape of the calibration curve, performing poorly where plateaus in atmospheric 14C concentration exist. We employ an ensemble of age-depth models to reconstruct a 1500 year accumulation history for a saltmarsh core recovered from Connecticut, USA based on a composite chronology comprising 26 AMS radiocarbon dates, 210Pb, 137Cs radionuclides and an historical pollen chronohorizon. The resulting record reveals non-linear accumulation during the late Holocene with a marked increase in rate around AD1800. With the exception of the interval between AD1500 and AD1800, all modelsproduce accumulation curves that agree to within ~10 cm at the century-scale. The accumulation rate increase around AD1800 is associated with the transition from a radiocarbon-based to a 210Pb dominated chronology. Whilst repeat analysis excluding the 210Pb data alters the precise timing and magnitude of this acceleration, a shift to faster accumulation compared to the long-term rate is a robust feature of the record and not simply an artefact of the switch in dating methods. Simulation indicates that a rise of similar magnitude to the post-AD1800 increase (detrended increase of ~16 cm) is theoretically constrained and detectable within the radiocarbon-dated portion of the record. The absence of such a signal suggests that the recent rate of accumulation is unprecedented in the last 1500 years. Our results indicate that reliable (sub)century-scale age-depth models can be developed from saltmarsh sequences, and that the vertical uncertainties associated with them translate to RSL reconstruction errors that are typically smaller than those associated with the most precise microfossil-based estimates of palaeomarsh-surface elevation

Effluent Organic Nitrogen (EON): Bioavailability and Photochemical and Salinity-Mediated Release

The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH4+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based on changes in DON concentrations, indicate that some fraction of the EON was removed and that the degree of EON removal varied between effluents and with salinity. Further, we caution that bioassay results should be interpreted within a broad context of detailed information on chemical characterization. EON from both WWTPs was also photoreactive, with labile NH4+ and dissolved primary amines released during exposure to sunlight. We also present the first data that demonstrate that when EON is exposed to higher salinities, increasing amounts of NH4+ are released, further facilitating EON use as effluent transits from freshwater through estuaries to the coast

The influence of light on nitrogen cycling and the primary nitrite maximum in a seasonally stratified sea

Author Posting. © The Author(s), 2011. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Progress In Oceanography 91 (2011): 545–560, doi:10.1016/j.pocean.2011.09.001.In the seasonally stratified Gulf of Aqaba Red Sea, both NO2- release by phytoplankton and NH4+ oxidation by nitrifying microbes contributed to the formation of a primary nitrite maximum (PNM) over different seasons and depths in the water column. In the winter and during the days immediately following spring stratification, NO2- formation was strongly correlated (R2=0.99) with decreasing irradiance and chlorophyll, suggesting that incomplete NO3- reduction by light limited phytoplankton was a major source of NO2-. However, as stratification progressed, NO2- continued to be generated below the euphotic depth by microbial NH4+ oxidation, likely due to differential photoinhibition of NH4+ and NO2- oxidizing populations. Natural abundance stable nitrogen isotope analyses revealed a decoupling of the δ15N and δ18O in the combined NO3- and NO2- pool, suggesting that assimilation and nitrification were co-occurring in surface waters. As stratification progressed, the δ15N of particulate N below the euphotic depth increased from -5‰ to up to +20‰. N uptake rates were also influenced by light; based on 15N tracer experiments, assimilation of NO3-, NO2-, and urea was more rapid in the light (434±24, 94±17, and 1194±48 nmol N L-1 day-1 respectively) than in the dark (58±14, 29±14, and 476±31 nmol N L-1 day-1 respectively). Dark NH4+ assimilation was 314±31 nmol N L-1 day-1, while light NH4+ assimilation was much faster, resulting in complete consumption of the 15N spike in less than 7 hour from spike addition. The overall rate of coupled urea mineralization and NH¬4+ oxidation (14.1±7.6 nmol N L-1 day-1) was similar to that of NH¬4+ oxidation alone (16.4±8.1 nmol N L-1 day-1), suggesting that for labile dissolved organic N compounds like urea, mineralization was not a rate limiting step for nitrification. Our results suggest that assimilation and nitrification compete for NH4+ and that N transformation rates throughout the water column are influenced by light over diel and seasonal cycles, allowing phytoplankton and nitrifying microbes to contribute jointly to PNM formation. We identify important factors that influence the N cycle throughout the year, including light intensity, substrate availability, and microbial community structure. These processes could be relevant to other regions worldwide where seasonal variability in mixing depth and stratification influence the contributions of phytoplankton and non-photosynthetic microbes to the N cycle.This research was supported under the North Atlantic Treaty Organization (NATO) Science for Peace Grant SfP 982161 to AP and AFP, a grant from the Koret Foundation to AP, a National Science Foundation Biological Oceanography grant to AP, the Israel Science Foundation grant 135/05 to AFP, and research grant 8330-06 from the Geological Society of America to KRMM

Effluent Organic Nitrogen (EON): Bioavailability and Photochemical and Salinity-Mediated Release

The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH₄⁺). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based on changes in DON concentrations, indicate that some fraction of the EON was removed and that the degree of EON removal varied between effluents and with salinity. Further, we caution that bioassay results should be interpreted within a broad context of detailed information on chemical characterization. EON from both WWTPs was also photoreactive, with labile NH₄⁺ and dissolved primary amines released during exposure to sunlight. We also present the first data that demonstrate that when EON is exposed to higher salinities, increasing amounts of NH₄⁺ are released, further facilitating EON use as effluent transits from freshwater through estuaries to the coast

Flow events drive patterns of phytoplankton distribution along a river-estuary-bay continuum

Freshwater flow events drive phytoplankton productivity in subtropical coastal river systems. However, few studies have the necessary temporal and spatial resolution to fully characterise the effect of events on the distribution of phytoplankton across the full river-estuary-bay continuum. The present study characterised the response of phytoplankton to high-flow events in an Australian subtropical system; and identified the primary drivers of this response. During high-flow events, the concentration of phytoplankton chlorophyll a (Chl a) initially declined in the estuary, a response primarily driven by the shortened water-residence time. In the bay, phytoplankton growth in the near-shore zone was light limited; however, nutrients stimulated phytoplankton growth on the seaward edge of the river plume. During the post-high-flow phase, the concentration of Chl a in the freshwater reaches peaked downstream, where catchment-derived nutrients accumulated. In the estuary, elevated nutrient loads stimulated phytoplankton growth upstream and downstream of the light-limited zone. In the bay, nitrogen availability declined, and Chl a declined with an increasing distance offshore. The phytoplankton response to events documented in the present study can be used to identify when and where phytoplankton in subtropical systems may be strongly influenced by changes in the magnitude of nutrient, sediment and freshwater loads associated with high-flow events which result from anthropogenic pressures within the catchment

Integrated Ocean Drilling Program Expedition 327 Preliminary Report: Juan de Fuca Ridge-Flank Hydrogeology The hydrogeologic architecture of basaltic oceanic crust: compartmentalization, anisotropy, microbiology, and crustal-scale properties on the eastern flank of Juan de Fuca Ridge, eastern Pacific Ocean, 5 July–5 September 2010

Integrated Ocean Drilling Program (IODP) Expedition 327 and related experiments focus on understanding fluid–rock interactions in young, upper ocean crust on the eastern flank of the Juan de Fuca Ridge, delineating the magnitude and distribution of hydrologic properties; the extent to which crustal compartments are connected or isolated (laterally and with depth); the rates and spatial extent of ridge-flank fluid circulation; and links between ridge-flank circulation, crustal alteration, and geomicrobial processes. Expedition 327 built on the achievements of IODP Expedition 301 and subsequent submersible and remotely operated vehicle (ROV) expeditions. Both drilling expeditions installed subseafloor borehole observatories ("CORKs") in basement holes to allow borehole conditions to recover to a more natural state after the dissipation of disturbances caused by drilling, casing, and other operations; provide a long-term monitoring and sampling presence for determining fluid pressure, temperature, composition, and microbiology; and facilitate the completion of active experiments to resolve crustal hydrogeologic conditions and processes.During Expedition 327, two basement holes were cored and drilled at Site U1362. Hole U1362A was cored and drilled to 528 meters below seafloor (mbsf) (292 meters subbasement [msb]), subjected to geophysical logging and hydrologic testing, and instrumented with a multilevel CORK observatory. Hole U1362B was drilled to 359 mbsf (117 msb), subjected to a 24 h pumping and tracer injection experiment, and instrumented with a single-level CORK observatory. Both CORK observatories include monitoring of pressure and temperature and downhole fluid and microbiology sampling. Wellhead samplers will be added and a long-term cross-hole test will be initiated during a postdrilling ROV expedition scheduled for Summer 2011. In addition, part of an instrument string deployed in Hole U1301B during Expedition 301 was recovered, and a replacement string of thermal sensors was installed. Finally, a program of shallow sediment coring was completed adjacent to Grizzly Bare outcrop, a suspected site of regional hydrothermal recharge. Thermal measurements and analyses of pore fluid and microbiological samples from a series of holes aligned radially from the outcrop edge will elucidate rates of fluid transport and evolution during the initial stages of ridge-flank hydrothermal circulation